Yes. The S5 can accept up to 128 Gb cards. Copied from the Samsung S5 Product page for Sprint on Bestbuy.com:
16GB internal memory plus microSD slot
Provides plenty of storage space for your contacts, music, apps and more. Expand storage up to 128GB by adding a microSD card (sold separately).
9 years, 4 months ago
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CPolarBear
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Moyock, NC