Yes. The Peel remote app will connect to most any brand of tv, dvd, or satellite box, especially a samsung. I took me less than 5 min to connect to my samsung tv and sony blu-ray player.
I have the UN55F8000BFXZA and the keyboard links through the BlueTooth settings in the menu. I have not had any issues with the keyboard and is a breeze to use. You can go to Samsung.com and find all kinds of manuals and tech info on the site. Hope this helps.